I guess I'm confused. As I see your question, the Post Mash and Pre Boil should be exactly the same. If you add additional sugar at, or toward, the end of the boil you shoild see those additions in the OG field.
BeerSmith counts sugar additions in the kettle as part of Preboil gravity. I just checked. I then changed the sugar to an extract and the same behavior remained true. The mash gravity in both cases was 1.072 and the preboil gravity was 1.077. Removing the extract from the recipe showed both mash & preboil gravity at 1.073. This behavior remained true in both all grain and partial mash assignments.
This is consistent with how BeerSmith 2.2 operated, where all sugars were part of the preboil number, regardless of source or when they were added.
If a grain, extract or sugar is marked as being added
after the boil, then the gravity does not show up in the preboil number, and this is new behavior in version 2.3. It'll show up in the OG, instead.
The extract (or sugar) must be categorized in the ingredient details as sugar, extract or dry extract for it to be properly assigned to a kettle addition, instead of mash. If marked as grain or adjunct, then BeerSmith assumes it will be part of the mash.