The boil volume doesn't make a difference, but the specific gravity of the boiling wort does make a difference. It is why many extract brewers hold 1/3 to 1/2 of their extract until the last fifteen minutes of the boil. With a lower gravity wort being boiled, the extraction of the Alpha Acids in the hops is more efficient. You get more IBU's from the same amount of hops, when boiling a lower gravity wort.
However, I noticed that your IBU's went up, when you reduced your boil volume, which would have raised your wort specific gravity in the boil. I would have expected your IBU's to go down, not up.
I'm a little puzzled by this.